Saturable absorption of intense hard X-rays in iron.

Yoneda, Hitoki; Inubushi, Yuichi; Yabashi, Makina; Katayama, Tetsuo; Ishikawa, Tetsuya; Ohashi, Haruhiko; Yumoto, Hirokatsu; Yamauchi, Kazuto et al. · Nat Commun · 2014

basic_science · Level V

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Abstract

In 1913, Maurice de Broglie discovered the presence of X-ray absorption bands of silver and bromine in photographic emulsion. Over the following century, X-ray absorption spectroscopy was established as a standard basis for element analysis, and further applied to advanced investigation of the structures and electronic states of complex materials. Here we show the first observation of an X-ray-induced change of absorption spectra of the iron K-edge for 7.1-keV ultra-brilliant X-ray free-electron laser pulses with an extreme intensity of 10(20) W cm(-2). The highly excited state yields a shift of the absorption edge and an increase of transparency by a factor of 10 with an improvement of the phase front of the transmitted X-rays. This finding, the saturable absorption of hard X-rays, opens a promising path for future innovations of X-ray science by enabling novel attosecond active optics, such as lasing and dynamical spatiotemporal control of X-rays.