Molecularly engineered dual-crosslinked hydrogel with ultrahigh mechanical strength, toughness, and good self-recovery.

Lin, Peng; Ma, Shuanhong; Wang, Xiaolong; Zhou, Feng · Adv Mater · 2015

basic_science · Level V

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Abstract

A molecularly engineered dual-crosslinked hydrogel with extraordinary mechanical properties is reported. The hydrogel network is formed with both chemical crosslinking and acrylic-Fe(III) coordination; these, respectively, impart the elasticity and enhance the mechanical properties by effectively dissipating energy. The optimal hydrogel achieves a tensile stress of ca. 6 MPa at a large elongation ratio (>7 times), a toughness of 27 MJ m(-3) , and a stiffness of ca. 2 MPa, and has good self-recovery properties.

Medical subject headings