Tunable quantum confinement in ultrathin, optically active semiconductor nanowires via reverse-reaction growth.

Loitsch, Bernhard; Rudolph, Daniel; Morkötter, Stefanie; Döblinger, Markus; Grimaldi, Gianluca; Hanschke, Lukas; Matich, Sonja; Parzinger, Eric et al. · Adv Mater · 2015

basic_science · Level V

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Abstract

A unique growth scheme is demonstrated to realize ultrathin GaAs nanowires on Si with sizes down to the sub-10 nm regime. While this scheme preserves the bulk-like crystal properties, correlated optical experiments reveal huge blueshifted photo-luminescence (up to ≈100 meV) with decreasing nanowire cross-section, demonstrating very strong quantum confinement effects.