Macroscopic, freestanding, and tubular graphene architectures fabricated via thermal annealing.
basic_science · Level V
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- Record sourced from PubMed, PMID 25738973.
- Also identified by DOI 10.1021/acsnano.5b00292.
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Abstract
Manipulation of individual graphene sheets/films into specific architectures at macroscopic scales is crucially important for practical uses of graphene. We present herein a versatile and robust method based on annealing of solid carbon precursors on nickel templates and thermo-assisted removal of poly(methyl methacrylate) under low vacuum of ∼0.6 Pa for fabrication of macroscopic, freestanding, and tubular graphene (TG) architectures. Specifically, the TG architectures can be obtained as individual and woven tubes with a diameter of ∼50 μm, a wall thickness in the range of 2.1-2.9 nm, a density of ∼1.53 mg·cm(-3), a thermal stability up to 600 °C in air, an electrical conductivity of ∼1.48 × 10(6) S·m(-1), and field emission current densities on the order of 10(4) A·cm(-2) at low applied electrical fields of 0.6-0.7 V·μm(-1). These properties show great promise for applications in flexible and lightweight electronics, electron guns, or X-ray tube sources.