Nonlinear elasticity and cavitation of a triblock copolymer gel.

Abstract

Polymer gels are subjected to large-strain deformation during their applications. The gel deformation at large-strain is non-linear and can often lead to failure of the material. Here, we report the large-strain deformation behavior of a physically cross-linked, swollen triblock copolymer gel, which displays unique strain-stiffening response at large-strain. Investigations were performed using large amplitude oscillatory shear (LAOS) and custom developed cavitation rheology techniques. The Gent constitutive equation, which considers finite extensibility of midblock, was fitted with the LAOS data, thereby, linking the estimated parameters from LAOS analysis to the structure of the gel. The pressure responses obtained from the cavitation experiments were modeled using neo-Hookean and Gent constitutive equations. Our results capture the failure behavior of a gel with finite chain extensibility, initiated from a defect within the gel.