Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles.

Chaudhari, Abhijeet K; Han, Intaek; Tan, Jin-Chong · Adv Mater · 2015

basic_science · Level V

Where this comes from

Abstract

A synergistic approach is described to engineer supramolecular hybrid materials based on metal-organic frameworks, encompassing HKUST-1 nanoparticles formed in situ, coexisting with an electrically conducting gel fiber network. The following findings are made: i) multistimuli-responsive structural transformation via reversible sol-gel switching and ii) radical conversion of a soft hybrid gel into a mechanically malleable, viscoelastic matter.