Relative Entropy and Optimization-Driven Coarse-Graining Methods in VOTCA.

Mashayak, S Y; Jochum, Mara N; Koschke, Konstantin; Aluru, N R; Rühle, Victor; Junghans, Christoph · PLoS One · 2015

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Abstract

We discuss recent advances of the VOTCA package for systematic coarse-graining. Two methods have been implemented, namely the downhill simplex optimization and the relative entropy minimization. We illustrate the new methods by coarse-graining SPC/E bulk water and more complex water-methanol mixture systems. The CG potentials obtained from both methods are then evaluated by comparing the pair distributions from the coarse-grained to the reference atomistic simulations. In addition to the newly implemented methods, we have also added a parallel analysis framework to improve the computational efficiency of the coarse-graining process.

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