Deciphering the Elementary Steps of Transport-Reaction Processes at Individual Ag Nanoparticles by 3D Superlocalization Microscopy.
basic_science · Level V
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- Record sourced from PubMed, PMID 26327450.
- Also identified by DOI 10.1021/acs.nanolett.5b02921.
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Abstract
Transport-reaction processes at individual Ag nanoparticles (NPs) are studied using electrochemistry coupled with in situ 3D light scattering microscopy. Electrochemistry is used to trigger a (i) diffusiophoretic transport mode capable of accelerating and preconcentrating NPs toward an electrode and (ii) subsequent diffusion-controlled oxidation of NPs. Individual NP dissolution rate, analyzed using optical modeling, suggests the intervention of insoluble products. New insights into diverse NPs behaviors highlight the strength of coupled optical-electrochemical 3D microscopies for single-NP studies.