A Solution-Processed Resonance Host for Highly Efficient Electrophosphorescent Devices with Extremely Low Efficiency Roll-off.

Tao, Ye; Guo, Xin; Hao, Lin; Chen, Runfeng; Li, Huanhuan; Chen, Yuehua; Zhang, Xinwen; Lai, Wenyong et al. · Adv Mater · 2015

basic_science · Level V

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Abstract

Solution-processible N-P=O resonance-host molecules are applied successfully in spin-coated phosphorescent light-emitting diodes (PHOLEDs) to selectively and self-adaptively tune the electrical properties for balanced charge transportation. The resonance-molecule-hosted PHOLEDs exhibit a high maximum quantum efficiency of 16.5% and a low efficiency roll-off down to 0.7%, highlighting the significant progress of these solution-processed PHOLEDs with high efficiency and flat efficiency roll-off achieved simultaneously.