Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba₃(ZnB₅O₁₀)PO₄.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 26459262.
- Also identified by DOI 10.1002/adma.201503951.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.