Tuning Band Alignment Using Interface Dipoles at the Pt/Anatase TiO₂ Interface.
basic_science · Level V
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- Record sourced from PubMed, PMID 26502952.
- Also identified by DOI 10.1002/adma.201503339.
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Abstract
The Schottky barrier heights at the Pt/TiO2 (001) junctions are modulated over 0.8 eV by inserting <1 nm of LaAlO3. The large electric field in the LaAlO3 is stabilized by preserving the continuity of in-plane lattice symmetry at the oxide interface. These results greatly expand the application of dipole engineering to versatile polycrystalline metal/binary oxide functional interfaces.