Injectable Self-Healing Glucose-Responsive Hydrogels with pH-Regulated Mechanical Properties.

Yesilyurt, Volkan; Webber, Matthew J; Appel, Eric A; Godwin, Colin; Langer, Robert; Anderson, Daniel G · Adv Mater · 2016

basic_science · Level V

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Abstract

Dynamically restructuring pH-responsive hydrogels are synthesized, employing dynamic covalent chemistry between phenylboronic acid and cis-diol modified poly(ethylene glycol) macromonomers. These gels display shear-thinning behavior, followed by a rapid structural recovery (self-healing). Size-dependent in vitro controlled and glucose-responsive release of proteins from the hydrogel network, as well as the biocompatibility of the gels, are evaluated both in vitro and in vivo.

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