Doping-Induced Carrier Density Modulation in Polymer Field-Effect Transistors.

Lee, Byoung Hoon; Bazan, Guillermo C; Heeger, Alan J · Adv Mater · 2016

basic_science · Level V

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Abstract

Controlled device parameters of high-mobility polymer field-effect transistors (FETs) are demonstrated by modest doping and charge compensation. Through fleeting chemical vapor treatments of aligned poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b']dithiophen-2-yl)-alt-[1,2,5]thiadiazolo-[3,4-c]pyridine] (PCDTPT) thin films as the charge transport layer in the FET channel, the FET properties are tailored by controlling doping concentration of the PCDTPT adjacent to metal electrodes.