Robust Crystalline Hybrid Solid with Multiple Channels Showing High Anhydrous Proton Conductivity and a Wide Performance Temperature Range.

Luo, Hong-Bin; Ren, Li-Te; Ning, Wei-Hua; Liu, Shao-Xian; Liu, Jian-Lan; Ren, Xiao-Ming · Adv Mater · 2016

basic_science · Level V

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Abstract

A proton conductor displaying high anhydrous proton conductivity (≈10(-2) S cm(-1)) and good performance over a broad temperature range is presented. This hybrid material is produced via doping HCl into open-framework chalcogenide(C2N2H10)(C2N2H9)2 Cu8 Sn3S12, and has cubopolyhedral cavities and multiple channels.