Alkaline Anion-Exchange Membranes Containing Mobile Ion Shuttles.
basic_science · Level V
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- Record sourced from PubMed, PMID 26972938.
- Also identified by DOI 10.1002/adma.201506199.
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Abstract
A new class of alkaline anion-exchange membranes containing mobile ion shuttles is developed. It is achieved by threading ionic linear guests into poly(crown ether) hosts via host-guest molecular interaction. The thermal- and pH-triggered shuttling of ionic linear guests remarkably increases the solvation-shell fluctuations in inactive hydrated hydroxide ion complexes (OH(-) (H2 O)4 ) and accelerates the OH(-) transport.