Anomalously slow relaxation of interacting liquid nanoclusters confined in a porous medium.

Abstract

Anomalously slow relaxation of clusters of a liquid confined in a disordered system of pores has been studied for the (water-L23 nanoporous medium) system. The evolution of the system of confined liquid clusters consists of a fast formation stage followed by slow relaxation of the system and its decay. The characteristic time for the formation of the initial state is τ(p)∼10 s after the reduction of excess pressure after complete filling. Anomalously slow relaxation has been observed for times of 10(1)-10(5) s, and decay has been observed at times of >10(5) s. The time dependence of the volume fraction θ of pores filled with the confined liquid is described by a power law θ∼t(-α) with the exponent α<0.15. The exponent α and temperature dependence α(T) are qualitatively described theoretically for the case of a slightly polydisperse medium in a mean-field approximation with the inclusion of the interaction of liquid clusters and averaging over various degenerate local configurations of clusters. In this approximation, slow relaxation is represented as a continuous transition through a sequence of metastable states of the system of clusters with a decreasing barrier.