Energy Transfer of Biexcitons in a Single Semiconductor Nanocrystal.

Abstract

Photoluminescence (PL) decay dynamics of multiexcitons in semiconductor nanocrystals (NCs) are dominated by the nonradiative Auger effect, making it difficult to explore their basic optical processes such as radiative recombination and energy transfer (ET). Here we constructed a single-particle ET system by attaching several acceptor dyes to the surface of a donor NC to study the ET of biexcitons at a single-NC level. By comparing the single-exciton and biexciton PL lifetimes of the same donor NC before and after the acceptor dyes were bleached, their respective ET lifetimes could be reliably extracted without the Auger influence. From statistical measurements on a large number of single ET particles, the average ET rate ratio between biexcitons and single excitons was estimated to be larger than four, and the same scaling rule could be naturally extended to their radiative rates.