Porous Carbon Spheres: Rational Design of Si/SiO2 @Hierarchical Porous Carbon Spheres as Efficient Polysulfide Reservoirs for High-Performance Li-S Battery (Adv. Mater. 16/2016).

Rehman, Sarish; Guo, Shaojun; Hou, Yanglong · Adv Mater · 2016

basic_science · Level V

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Abstract

S. Guo, Y. Hou, and S. Rehman develop a new class of silicon crosslinked with hierarchical porous carbon spheres usable as an efficient polysulfide reservoir for enhancing the performance of lithium-sulfur batteries. As described on page 3167, the developed hybrid material adsorbs negatively charged polysulfides via both chemical and physical adsorption. Remarkably, the hybrid spheres show a high specific capacity, an excellent rate capability and long cyclability.