Chiral Plasmonics Using Twisting along Cellulose Nanocrystals as a Template for Gold Nanoparticles.

Majoinen, Johanna; Hassinen, Jukka; Haataja, Johannes S; Rekola, Heikki T; Kontturi, Eero; Kostiainen, Mauri A; Ras, Robin H A; Törmä, Päivi et al. · Adv Mater · 2016

basic_science · Level V

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Abstract

The right-handed twist along aqueous dispersed cellulose nanocrystals allows right-handed chiral plasmonics upon electrostatic binding of gold nanoparticles in dilute environment, through tuning the particle sizes and concentrations. Simulations using nanoparticle coordinates from cryo-electron tomography confirm the experimental results. The finding suggests generalization for other chiral and helical colloidal templates for nanoscale chiral plasmonics.