Self-Assembled Organic Single Crystalline Nanosheet for Solution Processed High-Performance n-Channel Field-Effect Transistors.
basic_science · Level V
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- Record sourced from PubMed, PMID 27165653.
- Also identified by DOI 10.1002/adma.201506387.
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Abstract
Submillimeter sized n-channel organic single crystalline nanosheet based on dicyanodistyrylbenzene derivative, (2E,2'E)-3,3'-(2,5-dimethoxy-1,4-pheny-lene)bis(2-(5-(4-(trifluoromethyl)phenyl)thiophen-2-yl)acrylonitrile) (Me-4-TFPTA), is developed. Strong π-π interaction, hydrogen bonding interactions derived from cyano group (CN) as well as solvent inclusion along the lateral direction play a key role in forming nanosheet morphology. Me-4-TFPTA nanosheets exhibit excellent field-effect electron mobility of up to 7.81 cm(2) v(-1) s(-1) .