Recyclable Crosslinked Polymer Networks via One-Step Controlled Radical Polymerization.
basic_science · Level V
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- Record sourced from PubMed, PMID 27206061.
- Also identified by DOI 10.1002/adma.201600871.
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Abstract
A nitroxide-mediated polymerization strategy allows one-step synthesis of recyclable crosslinked polymeric materials from any monomers or polymers that contain carbon-carbon double bonds amenable to radical polymerization. The resulting materials with dynamic covalent bonds can show full property recovery after multiple melt-reprocessing recycles. This one-step strategy provides for both robust, relatively sustainable recyclability of crosslinked polymers and design of networks for advanced technologies.