Metal-Organic Covalent Network Chemical Vapor Deposition for Gas Separation.

Boscher, Nicolas D; Wang, Minghui; Perrotta, Alberto; Heinze, Katja; Creatore, Mariadriana; Gleason, Karen K · Adv Mater · 2016

basic_science · Level V

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Abstract

The chemical vapor deposition (CVD) polymerization of metalloporphyrin building units is demonstrated to provide an easily up-scalable one-step method toward the deposition of a new class of dense and defect-free metal-organic covalent network (MOCN) layers. The resulting hyper-thin and flexible MOCN layers exhibit outstanding gas-separation performances for multiple gas pairs.