Alternating strings and clusters in suspensions of charged colloids.

Everts, J C; van der Linden, M N; van Blaaderen, A; van Roij, R · Soft Matter · 2016

basic_science · Level V

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Abstract

We report the formation of alternating strings and clusters in a binary suspension of repulsive charged colloids with double layers larger than the particle size. Within a binary cell model we include many-body and charge-regulation effects under the assumption of a constant surface potential, and consider their repercussions on the two-particle interaction potential. We find that the formation of induced dipoles close to a charge-reversed state may explain the formation of these structures. Finally, we will touch upon the formation of dumbbells and small clusters in a one-component system, where the effective electrostatic interaction is always repulsive.