Surface-Driven Magnetotransport in Perovskite Nanocrystals.

Thi N'Goc, Ha Le; Mouafo, Louis Donald Notemgnou; Etrillard, Céline; Torres-Pardo, Almudena; Dayen, Jean-François; Rano, Simon; Rousse, Gwenaëlle; Laberty-Robert, Christel et al. · Adv Mater · 2017

basic_science · Level V

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Abstract

Unique insights into magnetotransport in 20 nm ligand-free La<sub>0.67</sub> Sr<sub>0.33</sub> MnO<sub>3</sub> perovskite nanocrystals of nearly perfect crystalline quality reveal a chemically altered 0.8 nm thick surface layer that triggers exceptionally large magnetoresistance at low temperature, independently of the spin polarization of the ferromagnetic core. This discovery shows how the nanoscale impacts magnetotransport in a material widely spread as electrode in hybrid spintronic devices.