Ultrathin Interface Regime of Core-Shell Magnetic Nanoparticles for Effective Magnetism Tailoring.
basic_science · Level V
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- Record sourced from PubMed, PMID 28045532.
- Also identified by DOI 10.1021/acs.nanolett.6b04016.
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Abstract
The magnetic exchange coupling interaction between hard and soft magnetic phases has been important for tailoring nanoscale magnetism, but spin interactions at the core-shell interface have not been well studied. Here, we systematically investigated a new interface phenomenon termed enhanced spin canting (ESC), which is operative when the shell thickness becomes ultrathin, a few atomic layers, and exhibits a large enhancement of magnetic coercivity (H<sub>C</sub>). We found that ESC arises not from the typical hard-soft exchange coupling but rather from the large magnetic surface anisotropy (K<sub>S</sub>) of the ultrathin interface. Due to this large increase in magnetism, ultrathin core-shell nanoparticles overreach the theoretical limit of magnetic energy product ((BH)<sub>max</sub>) and exhibit one of the largest values of specific loss power (SLP), which testifies to their potential capability as an effective mediator of magnetic energy conversion.