Microfluidic pumping by micromolar salt concentrations.

Niu, Ran; Kreissl, Patrick; Brown, Aidan T; Rempfer, Georg; Botin, Denis; Holm, Christian; Palberg, Thomas; de Graaf, Joost · Soft Matter · 2017

basic_science · Level V

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Abstract

An ion-exchange-resin-based microfluidic pump is introduced that utilizes trace amounts of ions to generate fluid flows. We show experimentally that our pump operates in almost deionized water for periods exceeding 24 h and induces fluid flows of μm s<sup>-1</sup> over hundreds of μm. This flow displays a far-field, power-law decay which is characteristic of two-dimensional (2D) flow when the system is strongly confined and of three-dimensional (3D) flow when it is not. Using theory and numerical calculations we demonstrate that our observations are consistent with electroosmotic pumping driven by μmol L<sup>-1</sup> ion concentrations in the sample cell that serve as 'fuel' to the pump. Our study thus reveals that trace amounts of charge carriers can produce surprisingly strong fluid flows; an insight that should benefit the design of a new class of microfluidic pumps that operate at very low fuel concentrations.