Accommodating High Transformation Strains in Battery Electrodes via the Formation of Nanoscale Intermediate Phases: Operando Investigation of Olivine NaFePO<sub>4</sub>.

Xiang, Kai; Xing, Wenting; Ravnsbæk, Dorthe B; Hong, Liang; Tang, Ming; Li, Zheng; Wiaderek, Kamila M; Borkiewicz, Olaf J et al. · Nano Lett · 2017

basic_science · Level V

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Abstract

Virtually all intercalation compounds exhibit significant changes in unit cell volume as the working ion concentration varies. Na<sub>x</sub>FePO<sub>4</sub> (0 < x < 1, NFP) olivine, of interest as a cathode for sodium-ion batteries, is a model for topotactic, high-strain systems as it exhibits one of the largest discontinuous volume changes (∼17% by volume) during its first-order transition between two otherwise isostructural phases. Using synchrotron radiation powder X-ray diffraction (PXD) and pair distribution function (PDF) analysis, we discover a new strain-accommodation mechanism wherein a third, amorphous phase forms to buffer the large lattice mismatch between primary phases. The amorphous phase has short-range order over ∼1nm domains that is characterized by a and b parameters matching one crystalline end-member phase and a c parameter matching the other, but is not detectable by powder diffraction alone. We suggest that this strain-accommodation mechanism may generally apply to systems with large transformation strains.