C<sub>3</sub> N-A 2D Crystalline, Hole-Free, Tunable-Narrow-Bandgap Semiconductor with Ferromagnetic Properties.
basic_science · Level V
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- Record sourced from PubMed, PMID 28240434.
- Also identified by DOI 10.1002/adma.201605625.
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Abstract
Graphene has initiated intensive research efforts on 2D crystalline materials due to its extraordinary set of properties and the resulting host of possible applications. Here the authors report on the controllable large-scale synthesis of C<sub>3</sub> N, a 2D crystalline, hole-free extension of graphene, its structural characterization, and some of its unique properties. C<sub>3</sub> N is fabricated by polymerization of 2,3-diaminophenazine. It consists of a 2D honeycomb lattice with a homogeneous distribution of nitrogen atoms, where both N and C atoms show a D<sub>6h</sub> -symmetry. C<sub>3</sub> N is a semiconductor with an indirect bandgap of 0.39 eV that can be tuned to cover the entire visible range by fabrication of quantum dots with different diameters. Back-gated field-effect transistors made of single-layer C<sub>3</sub> N display an on-off current ratio reaching 5.5 × 10<sup>10</sup> . Surprisingly, C<sub>3</sub> N exhibits a ferromagnetic order at low temperatures (<96 K) when doped with hydrogen. This new member of the graphene family opens the door for both fundamental basic research and possible future applications.