Anisotropic MoS<sub>2</sub> Nanosheets Grown on Self-Organized Nanopatterned Substrates.
basic_science · Level V
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- Record sourced from PubMed, PMID 28294440.
- Also identified by DOI 10.1002/adma.201605785.
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Abstract
Manipulating the anisotropy in 2D nanosheets is a promising way to tune or trigger functional properties at the nanoscale. Here, a novel approach is presented to introduce a one-directional anisotropy in MoS<sub>2</sub> nanosheets via chemical vapor deposition (CVD) onto rippled patterns prepared on ion-sputtered SiO<sub>2</sub> /Si substrates. The optoelectronic properties of MoS<sub>2</sub> are dramatically affected by the rippled MoS<sub>2</sub> morphology both at the macro- and the nanoscale. In particular, strongly anisotropic phonon modes are observed depending on the polarization orientation with respect to the ripple axis. Moreover, the rippled morphology induces localization of strain and charge doping at the nanoscale, thus causing substantial redshifts of the phonon mode frequencies and a topography-dependent modulation of the MoS<sub>2</sub> workfunction, respectively. This study paves the way to a controllable tuning of the anisotropy via substrate pattern engineering in CVD-grown 2D nanosheets.