MoS₂ /Celgard Separator as Efficient Polysulfide Barrier for Long-Life Lithium-Sulfur Batteries.

Abstract

A high lithium conductive MoS₂ /Celgard composite separator is reported as efficient polysulfides barrier in Li-S batteries. Significantly, thanks to the high density of lithium ions on MoS₂ surface, this composite separator shows high lithium conductivity, fast lithium diffusion, and facile lithium transference. When used in Li-S batteries, the separator is proven to be highly efficient for depressing polysulfides shuttle, leading to high and long cycle stability. With 65% of sulfur loading, the device with MoS₂ /Celgard separator delivers an initial capacity of 808 mAh g^-1 and a substantial capacity of 401 mAh g^-1 after 600 cycles, corresponding to only 0.083% of capacity decay per cycle that is comparable to the best reported result so far. In addition, the Coulombic efficiency remains more than 99.5% during all 600 cycles, disclosing an efficient ionic sieve preventing polysulfides migration to the anode while having negligible influence on Li⁺ ions transfer across the separator. The strategy demonstrated in this work will open the door toward developing efficient separators with flexible 2D materials beyond graphene for energy-storage devices.