Ultrafast Formation of Amorphous Bimetallic Hydroxide Films on 3D Conductive Sulfide Nanoarrays for Large-Current-Density Oxygen Evolution Electrocatalysis.
basic_science · Level V
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- Record sourced from PubMed, PMID 28370573.
- Also identified by DOI 10.1002/adma.201700404.
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Abstract
Developing nonprecious oxygen evolution electrocatalysts that can work well at large current densities is of primary importance in a viable water-splitting technology. Herein, a facile ultrafast (5 s) synthetic approach is reported that produces a novel, efficient, non-noble metal oxygen-evolution nano-electrocatalyst that is composed of amorphous Ni-Fe bimetallic hydroxide film-coated, nickel foam (NF)-supported, Ni<sub>3</sub> S<sub>2</sub> nanosheet arrays. The composite nanomaterial (denoted as Ni-Fe-OH@Ni<sub>3</sub> S<sub>2</sub> /NF) shows highly efficient electrocatalytic activity toward oxygen evolution reaction (OER) at large current densities, even in the order of 1000 mA cm<sup>-2</sup> . Ni-Fe-OH@Ni<sub>3</sub> S<sub>2</sub> /NF also gives an excellent catalytic stability toward OER both in 1 m KOH solution and in 30 wt% KOH solution. Further experimental results indicate that the effective integration of high catalytic reactivity, high structural stability, and high electronic conductivity into a single material system makes Ni-Fe-OH@Ni<sub>3</sub> S<sub>2</sub> /NF a remarkable catalytic ability for OER at large current densities.