Ultrafast Synthesis of Novel Hexagonal Phase NaBiF₄ Upconversion Nanoparticles at Room Temperature.

Abstract

Upconversion (UC) nanoparticles (UCNPs) have evoked considerable attention in many fields owing to their fascinating features. However, rigorous synthesis conditions and expensive raw materials often limit their further applications. Here, a novel hexagonal phase NaBiF₄ UC matrix through a very facile method (one min only at room temperature) is synthesized. The nanoparticles show good monodispersity with uniform size. Under the 980 nm irradiation, Yb³⁺ /Ln³⁺ (Ln = Er, Ho, Tm) codoped NaBiF₄ nanoparticles show excellent UC luminescence (UCL). This super facile synthesis strategy and excellent matrix materials enable to achieve UCL in such low temperature, opening a new gateway for the UCNPs applied to a variety of areas in the future.