Pyrolysis of Helical Coordination Polymers for Metal-Sulfide-Based Helices with Broadband Chiroptical Activity.
basic_science · Level V
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- Record sourced from PubMed, PMID 28399369.
- Also identified by DOI 10.1021/acsnano.7b00103.
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Abstract
Fabrication of chiroptical materials with broadband response in the visible light region is vital to fully realize their potential applications. One way to achieve broadband chiroptical activity is to fabricate chiral nanostructures from materials that exhibit broadband absorption in the visible light region. However, the compounds used for chiroptical materials have predominantly been limited to materials with narrowband spectral response. Here, we synthesize Ag<sub>2</sub>S-based nanohelices derived from helical coordination polymers. The right- and left-handed coordination helices used as precursors are prepared from l- and d-glutathione with Ag<sup>+</sup> and a small amount of Cu<sup>2+</sup>. The pyrolysis of the coordination helices yields right- and left-handed helices of Cu<sub>0.12</sub>Ag<sub>1.94</sub>S/C, which exhibit chiroptical activity spanning the entire visible light region. Finite element method simulations substantiate that the broadband chiroptical activity is attributed to synergistic broadband light absorption and light scattering. Furthermore, another series of Cu<sub>0.10</sub>Ag<sub>1.90</sub>S/C nanohelices are synthesized by choosing the l- or d-Glu-Cys as starting materials. The pitch length of nanohelicies is controlled by changing the peptides, which alters their chiroptical properties. The pyrolysis of coordination helices enables one to fabricate helical Ag<sub>2</sub>S-based materials that enable broadband chiroptical activity but have not been explored owing to the lack of synthetic routes.