Time-reversal symmetry breaking hidden order in Sr<sub>2</sub>(Ir,Rh)O<sub>4</sub>.

Jeong, Jaehong; Sidis, Yvan; Louat, Alex; Brouet, Véronique; Bourges, Philippe · Nat Commun · 2017

basic_science · Level V

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Abstract

Layered 5d transition iridium oxides, Sr<sub>2</sub>(Ir,Rh)O<sub>4</sub>, are described as unconventional Mott insulators with strong spin-orbit coupling. The undoped compound, Sr<sub>2</sub>IrO<sub>4</sub>, is a nearly ideal two-dimensional pseudospin-1/2 Heisenberg antiferromagnet, similarly to the insulating parent compound of high-temperature superconducting copper oxides. Using polarized neutron diffraction, we here report a hidden magnetic order in pure and doped Sr<sub>2</sub>(Ir,Rh)O<sub>4</sub>, distinct from the usual antiferromagnetic pseudospin ordering. We find that time-reversal symmetry is broken while the lattice translation invariance is preserved in the hidden order phase. The onset temperature matches that of the odd-parity hidden order recently highlighted using optical second-harmonic generation experiments. The novel magnetic order and broken symmetries can be explained by the loop-current model, previously predicted for the copper oxide superconductors.