Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 28485395.
- Also identified by DOI 10.1038/ncomms15377 and PMC identifier 5436140.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Highly active and robust eletcrocatalysts based on earth-abundant elements are desirable to generate hydrogen and oxygen as fuels from water sustainably to replace noble metal materials. Here we report an approach to synthesize porous hybrid nanostructures combining amorphous nickel-cobalt complexes with 1T phase molybdenum disulfide (MoS<sub>2</sub>) via hydrazine-induced phase transformation for water splitting. The hybrid nanostructures exhibit overpotentials of 70 mV for hydrogen evolution and 235 mV for oxygen evolution at 10 mA cm<sup>-2</sup> with long-term stability, which have superior kinetics for hydrogen- and oxygen-evolution with Tafel slope values of 38.1 and 45.7 mV dec<sup>-1</sup>. Moreover, we achieve 10 mA cm<sup>-2</sup> at a low voltage of 1.44 V for 48 h in basic media for overall water splitting. We propose that such performance is likely due to the complete transformation of MoS<sub>2</sub> to metallic 1T phase, high porosity and stabilization effect of nickel-cobalt complexes on 1T phase MoS<sub>2</sub>.