Anthropogenic iron oxide aerosols enhance atmospheric heating.

Moteki, Nobuhiro; Adachi, Kouji; Ohata, Sho; Yoshida, Atsushi; Harigaya, Tomoo; Koike, Makoto; Kondo, Yutaka · Nat Commun · 2017

basic_science · Level V

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Abstract

Combustion-induced carbonaceous aerosols, particularly black carbon (BC) and brown carbon (BrC), have been largely considered as the only significant anthropogenic contributors to shortwave atmospheric heating. Natural iron oxide (FeO<sub>x</sub>) has been recognized as an important contributor, but the potential contribution of anthropogenic FeO<sub>x</sub> is unknown. In this study, we quantify the abundance of FeO<sub>x</sub> over East Asia through aircraft measurements using a modified single-particle soot photometer. The majority of airborne FeO<sub>x</sub> particles in the continental outflows are of anthropogenic origin in the form of aggregated magnetite nanoparticles. The shortwave absorbing powers (P<sub>abs</sub>) attributable to FeO<sub>x</sub> and to BC are calculated on the basis of their size-resolved mass concentrations and the mean P<sub>abs</sub>(FeO<sub>x</sub>)/P<sub>abs</sub>(BC) ratio in the continental outflows is estimated to be at least 4-7%. We demonstrate that in addition to carbonaceous aerosols the aggregate of magnetite nanoparticles is a significant anthropogenic contributor to shortwave atmospheric heating.