Tracing the oxygen isotope composition of the upper Earth's atmosphere using cosmic spherules.

Pack, Andreas; Höweling, Andres; Hezel, Dominik C; Stefanak, Maren T; Beck, Anne-Katrin; Peters, Stefan T M; Sengupta, Sukanya; Herwartz, Daniel et al. · Nat Commun · 2017

basic_science · Level V

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Abstract

Molten I-type cosmic spherules formed by heating, oxidation and melting of extraterrestrial Fe,Ni metal alloys. The entire oxygen in these spherules sources from the atmosphere. Therefore, I-type cosmic spherules are suitable tracers for the isotopic composition of the upper atmosphere at altitudes between 80 and 115 km. Here we present data on I-type cosmic spherules collected in Antarctica. Their composition is compared with the composition of tropospheric O<sub>2</sub>. Our data suggest that the Earth's atmospheric O<sub>2</sub> is isotopically homogenous up to the thermosphere. This makes fossil I-type micrometeorites ideal proxies for ancient atmospheric CO<sub>2</sub> levels.