Observing electron localization in a dissociating H<sub>2</sub><sup>+</sup> molecule in real time.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 28621332.
- Also identified by DOI 10.1038/ncomms15849 and PMC identifier 5481751.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Dissociation of diatomic molecules with odd number of electrons always causes the unpaired electron to localize on one of the two resulting atomic fragments. In the simplest diatomic molecule H<sub>2</sub><sup>+</sup> dissociation yields a hydrogen atom and a proton with the sole electron ending up on one of the two nuclei. That is equivalent to breaking of a chemical bond-the most fundamental chemical process. Here we observe such electron localization in real time by performing a pump-probe experiment. We demonstrate that in H<sub>2</sub><sup>+</sup> electron localization is complete in just 15 fs when the molecule's internuclear distance reaches 8 atomic units. The measurement is supported by a theoretical simulation based on numerical solution of the time-dependent Schrödinger equation. This observation advances our understanding of detailed dynamics of molecular dissociation.