Photoresponsive Smart Coloration Electrochromic Supercapacitor.
basic_science · Level V
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- Record sourced from PubMed, PMID 28640386.
- Also identified by DOI 10.1002/adma.201606728.
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Abstract
Electrochromic devices have been widely adopted in energy saving applications by taking advantage of the electrode coloration, but it is critical to develop a new electrochromic device that can undergo smart coloration and can have a wide spectrum in transmittance in response to input light intensity while also functioning as a rechargeable energy storage system. In this study, a photoresponsive electrochromic supercapacitor based on cellulose-nanofiber/Ag-nanowire/reduced-graphene-oxide/WO<sub>3</sub> -composite electrode that is capable of undergoing "smart" reversible coloration while simultaneously functioning as a reliable energy-storage device is developed. The fabricated device exhibits a high coloration efficiency of 64.8 cm<sup>2</sup> C<sup>-1</sup> and electrochemical performance with specific capacitance of 406.0 F g<sup>-1</sup> , energy/power densities of 40.6-47.8 Wh kg<sup>-1</sup> and 6.8-16.9 kW kg<sup>-1</sup> . The electrochromic supercapacitor exhibits excellent cycle reliability, where 75.0% and 94.1% of its coloration efficiency and electrochemical performance is retained, respectively, beyond 10 000 charge-discharge cycles. Cyclic fatigue tests show that the developed device is mechanically durable and suitable for wearable electronics applications. The smart electrochromic supercapacitor system is then integrated with a solar sensor to enable photoresponsive coloration where the transmittance changes in response to varying light intensity.