Comment on "Active sites for CO<sub>2</sub> hydrogenation to methanol on Cu/ZnO catalysts".

Nakamura, Junji; Fujitani, Tadahiro; Kuld, Sebastian; Helveg, Stig; Chorkendorff, Ib; Sehested, Jens · Science · 2017

editorial · Level V

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Abstract

Kattel <i>et al</i> (Reports, 24 March 2017, p. 1296) report that a zinc on copper (Zn/Cu) surface undergoes oxidation to zinc oxide/copper (ZnO/Cu) during carbon dioxide (CO<sub>2</sub>) hydrogenation to methanol and conclude that the Cu-ZnO interface is the active site for methanol synthesis. Similar experiments conducted two decades ago by Fujitani and Nakamura <i>et al</i> demonstrated that Zn is attached to formate rather than being fully oxidized.

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