Correlations in suspensions confined between viscoelastic surfaces: Noncontact microrheology.

Abstract

We study theoretically the velocity cross-correlations of a viscous fluid confined in a slit between two viscoelastic media. We analyze the effect of these correlations on the motions of particles suspended in the fluid. The compliance of the confining boundaries gives rise to a long-ranged pair correlation, decaying only as 1/r with the interparticle distance r. We show how this long-ranged effect may be used to extract the viscoelastic properties of the confining media without embedding tracer particles in them. We discuss the remarkable robustness of such a potential technique with respect to details of the confinement, and its expected statistical advantages over standard two-point microrheology.