Two-Dimensional Vanadium Carbide (MXene) as a High-Capacity Cathode Material for Rechargeable Aluminum Batteries.

Abstract

Rechargeable aluminum batteries (Al batteries) can potentially be safer, cheaper, and deliver higher energy densities than those of commercial Li-ion batteries (LIBs). However, due to the very high charge density of Al³⁺ cations and their strong interactions with the host lattice, very few cathode materials are known to be able to reversibly intercalate these ions. Herein, a rechargeable Al battery based on a two-dimensional (2D) vanadium carbide (V₂CT_x) MXene cathode is reported. The reversible intercalation of Al³⁺ cations between the MXene layers is suggested to be the mechanism for charge storage. It was found that the electrochemical performance could be significantly improved by converting multilayered V₂CT_x particles to few-layer sheets. With specific capacities of more than 300 mAh g^-1 at high discharge rates and relatively high discharge potentials, V₂CT_x MXene electrodes show one of the best performances among the reported cathode materials for Al batteries. This study can lead to foundations for the development of high-capacity and high energy density rechargeable Al batteries by showcasing the potential of a large family of intercalation-type cathode materials based on MXenes.