A General Method for the Chemical Synthesis of Large-Scale, Seamless Transition Metal Dichalcogenide Electronics.

Li, Li; Guo, Yichuan; Sun, Yuping; Yang, Long; Qin, Liang; Guan, Shouliang; Wang, Jinfen; Qiu, Xiaohui et al. · Adv Mater · 2018

basic_science · Level V

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Abstract

The capability to directly build atomically thin transition metal dichalcogenide (TMD) devices by chemical synthesis offers important opportunities to achieve large-scale electronics and optoelectronics with seamless interfaces. Here, a general approach for the chemical synthesis of a variety of TMD (e.g., MoS<sub>2</sub> , WS<sub>2</sub> , and MoSe<sub>2</sub> ) device arrays over large areas is reported. During chemical vapor deposition, semiconducting TMD channels and metallic TMD/carbon nanotube (CNT) hybrid electrodes are simultaneously formed on CNT-patterned substrate, and then coalesce into seamless devices. Chemically synthesized TMD devices exhibit attractive electrical and mechanical properties. It is demonstrated that chemically synthesized MoS<sub>2</sub> -MoS<sub>2</sub> /CNT devices have Ohmic contacts between MoS<sub>2</sub> /CNT hybrid electrodes and MoS<sub>2</sub> channels. In addition, MoS<sub>2</sub> -MoS<sub>2</sub> /CNT devices show greatly enhanced mechanical stability and photoresponsivity compared with conventional gold-contacted devices, which makes them suitable for flexible optoelectronics. Accordingly, a highly flexible pixel array based on chemically synthesized MoS<sub>2</sub> -MoS<sub>2</sub> /CNT photodetectors is applied for image sensing.