Preparation and characterization of silane-modified SiO₂ particles reinforced resin composites with fluorinated acrylate polymer.

Abstract

A series of fluorinated dental resin composites were prepared with two kinds of SiO₂ particles. Bis-GMA (bisphenol A-glycerolate dimethacrylate)/4-TF-PQEA (fluorinated acrylate monomer)/TEGDMA (triethylene glycol dimethacrylate) (40/30/30, wt/wt/wt) was introduced as resin matrix. SiO₂ nanopartices (30nm) and SiO₂ microparticles (0.3µm) were silanized with 3-methacryloxypropyl trimethoxysilane (γ-MPS) and used as fillers. After mixing the resin matrix with 0%, 10%, 20%, 30% SiO₂ nanopartices and 0%, 10%, 20%, 30%, 40%, 50% SiO₂ microparticles, respectively, the fluorinated resin composites were obtained. Properties including double bond conversion (DC), polymerization shrinkage (PS), water sorption (W_p), water solubility (W_y), mechanical properties and cytotoxicity were investigated in comparison with those of neat resin system. The results showed that, filler particles could improve the overall performance of resin composites, particularly in improving mechanical properties and reducing PS of composites along with the addition of filler loading. Compared to resin composites containing SiO₂ microparticles, SiO₂ nanoparticles resin composites had higher DC, higher mechanical properties, lower PS and lower W_p under the same filler content. Especially, 50% SiO₂ microparticles reinforced resins exhibited the best flexural strength (104.04 ± 7.40MPa), flexural modulus (5.62 ± 0.16GPa), vickers microhardness (37.34 ± 1.13 HV), compressive strength (301.54 ± 5.66MPa) and the lowest polymerization (3.42 ± 0.22%).