Directed gas phase formation of silicon dioxide and implications for the formation of interstellar silicates.

Yang, Tao; Thomas, Aaron M; Dangi, Beni B; Kaiser, Ralf I; Mebel, Alexander M; Millar, Tom J · Nat Commun · 2018

basic_science · Level V

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Abstract

Interstellar silicates play a key role in star formation and in the origin of solar systems, but their synthetic routes have remained largely elusive so far. Here we demonstrate in a combined crossed molecular beam and computational study that silicon dioxide (SiO<sub>2</sub>) along with silicon monoxide (SiO) can be synthesized via the reaction of the silylidyne radical (SiH) with molecular oxygen (O<sub>2</sub>) under single collision conditions. This mechanism may provide a low-temperature path-in addition to high-temperature routes to silicon oxides in circumstellar envelopes-possibly enabling the formation and growth of silicates in the interstellar medium necessary to offset the fast silicate destruction.