Generalized thermodynamics of phase equilibria in scalar active matter.

Solon, Alexandre P; Stenhammar, Joakim; Cates, Michael E; Kafri, Yariv; Tailleur, Julien · Phys Rev E · 2018

basic_science · Level V

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Abstract

Motility-induced phase separation (MIPS) arises generically in fluids of self-propelled particles when interactions lead to a kinetic slowdown at high densities. Starting from a continuum description of scalar active matter akin to a generalized Cahn-Hilliard equation, we give a general prescription for the mean densities of coexisting phases in flux-free steady states that amounts, at a hydrodynamics scale, to extremizing an effective free energy. We illustrate our approach on two well-known models: self-propelled particles interacting either through a density-dependent propulsion speed or via direct pairwise forces. Our theory accounts quantitatively for their phase diagrams, providing a unified description of MIPS.