Multishelled Si@Cu Microparticles Supported on 3D Cu Current Collectors for Stable and Binder-free Anodes of Lithium-Ion Batteries.
basic_science · Level V
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- Record sourced from PubMed, PMID 29630825.
- Also identified by DOI 10.1021/acsnano.8b00703.
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Abstract
Silicon has proved to be a promising anode material of high-specific capacity for the next-generation lithium ion batteries (LIBs). However, during repeated discharge/charge cycles, Si-based electrodes, especially those in microscale size, pulverize and lose electrical contact with the current collectors due to large volume expansion. Here, we introduce a general method to synthesize Cu@M (M = Si, Al, C, SiO<sub>2</sub>, Si<sub>3</sub>N<sub>4</sub>, Ag, Ti, Ta, SnIn<sub>2</sub>O<sub>5</sub>, Au, V, Nb, W, Mg, Fe, Ni, Sn, ZnO, TiN, Al<sub>2</sub>O<sub>3</sub>, HfO<sub>2</sub>, and TiO<sub>2</sub>) core-shell nanowire arrays on Cu substrates. The resulting Cu@Si nanowire arrays were employed as LIB anodes that can be reused via HCl etching and H<sub>2</sub>-reduction. Multishelled Cu@Si@Cu microparticles supported on 3D Cu current collectors were further prepared as stable and binder-free LIB anodes. This 3D Cu@Si@Cu structure allows the interior conductive Cu network to effectively accommodate the volume expansion of the electrode and facilitates the contact between the Cu@Si@Cu particles and the current collectors during the repeated insertion/extraction of lithium ions. As a result, the 3D Cu@Si@Cu microparticles at a high Si-loading of 1.08 mg/cm<sup>2</sup> showed a capacity retention of 81% after 200 cycles. In addition, charging tests of 3D Cu@Si@Cu-LiFePO<sub>4</sub> full cells by a triboelectric nanogenerator with a pulsed current demonstrated that LIBs with silicon anodes can effectively store energy delivered by mechanical energy harvesters.