Ambipolar ferromagnetism by electrostatic doping of a manganite.

Zheng, L M; Wang, X Renshaw; Lü, W M; Li, C J; Paudel, T R; Liu, Z Q; Huang, Z; Zeng, S W et al. · Nat Commun · 2018

basic_science · Level V

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Abstract

Complex-oxide materials exhibit physical properties that involve the interplay of charge and spin degrees of freedom. However, an ambipolar oxide that is able to exhibit both electron-doped and hole-doped ferromagnetism in the same material has proved elusive. Here we report ambipolar ferromagnetism in LaMnO<sub>3</sub>, with electron-hole asymmetry of the ferromagnetic order. Starting from an undoped atomically thin LaMnO<sub>3</sub> film, we electrostatically dope the material with electrons or holes according to the polarity of a voltage applied across an ionic liquid gate. Magnetotransport characterization reveals that an increase of either electron-doping or hole-doping induced ferromagnetic order in this antiferromagnetic compound, and leads to an insulator-to-metal transition with colossal magnetoresistance showing electron-hole asymmetry. These findings are supported by density functional theory calculations, showing that strengthening of the inter-plane ferromagnetic exchange interaction is the origin of the ambipolar ferromagnetism. The result raises the prospect of exploiting ambipolar magnetic functionality in strongly correlated electron systems.