A standing molecule as a single-electron field emitter.

Abstract

Scanning probe microscopy makes it possible to image and spectroscopically characterize nanoscale objects, and to manipulate^1-3 and excite^4-8 them; even time-resolved experiments are now routinely achieved^9,10. This combination of capabilities has enabled proof-of-principle demonstrations of nanoscale devices, including logic operations based on molecular cascades ¹¹ , a single-atom transistor ¹² , a single-atom magnetic memory cell ¹³ and a kilobyte atomic memory ¹⁴ . However, a key challenge is fabricating device structures that can overcome their attraction to the underlying surface and thus protrude from the two-dimensional flatlands of the surface. Here we demonstrate the fabrication of such a structure: we use the tip of a scanning probe microscope to lift a large planar aromatic molecule (3,4,9,10-perylenetetracarboxylic-dianhydride) into an upright, standing geometry on a pedestal of two metal (silver) adatoms. This atypical and surprisingly stable upright orientation of the single molecule, which under all known circumstances adsorbs flat on metals^15,16, enables the system to function as a coherent single-electron field emitter. We anticipate that other metastable adsorbate configurations might also be accessible, thereby opening up the third dimension for the design of functional nanostructures on surfaces.