Dirac electrons in a dodecagonal graphene quasicrystal.

Ahn, Sung Joon; Moon, Pilkyung; Kim, Tae-Hoon; Kim, Hyun-Woo; Shin, Ha-Chul; Kim, Eun Hye; Cha, Hyun Woo; Kahng, Se-Jong et al. · Science · 2018

basic_science · Level V

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Abstract

Quantum states of quasiparticles in solids are dictated by symmetry. We have experimentally demonstrated quantum states of Dirac electrons in a two-dimensional quasicrystal without translational symmetry. A dodecagonal quasicrystalline order was realized by epitaxial growth of twisted bilayer graphene rotated exactly 30°. We grew the graphene quasicrystal up to a millimeter scale on a silicon carbide surface while maintaining the single rotation angle over an entire sample and successfully isolated the quasicrystal from a substrate, demonstrating its structural and chemical stability under ambient conditions. Multiple Dirac cones replicated with the 12-fold rotational symmetry were observed in angle-resolved photoemission spectra, which revealed anomalous strong interlayer coupling with quasi-periodicity. Our study provides a way to explore physical properties of relativistic fermions with controllable quasicrystalline orders.